Facilities and Methods


Facilities

Our lab currently offers the following instrumentation and apparatus:

  • Nitrogen glovebox with spinner and thermal evaporator
  • Oxford Maglab cryostat
  • Confocal Optical Microscope
  • Ocean Optics UV/Vis Dual Grating Spectrometer
  • Park Scientific Autoprobe CP Scanning Probe Microscope
  • n&k analyzer for optical analysis of thin films
  • several GPIB programmable measurement and power supply units
  • Nicolet Digital Scope
  • SRI Lock In Amplifier
  • Velonex high power pulse generator
  • EG&G Model 362 scanning potentiostat
  • PerkinElmer LS 45 luminescence spectrometer

Cyclic Voltammetry


Methods

The experimental methods employed are:

  • Current/radiance vs voltage curves to characterize polymer LEDs for their performance (brightness, quantum efficiency...) and for the underlying physics. Temperature dependance is studied using a cryostat. Radiance (W/cm2) is measured with a Si-photodiode that has been calibrated with an integrating sphere and a calibrated halogen lamp.
  • Emissionspectra analysis and CIE color coordinates calculation
  • Photovoltaic measurements with a Xenon lamp
  • Transport studies and 1/f noise analysis at the metal insulator transition of carbon black polymer composites are studied using the cryostat.
  • The Scanning Probe Microscope allows surface characterization and imaging down to the nanometer scale in different operation modes (Atomic Force-, Noncontact- , Scanning Tunneling-Mode)
  • Photoluminescence studies with the confocal optical microscope with micrometer resolution
  • Optical analysis of thin films yields determination of film thicknesses by measuring reflectivity- and transmission-spectra
  • Lifetime studies with automated setup
  • Impedance spectroscopy for the determination of capacitance vs bias curves and equivalent circuit models of polymer devices
  • Photoluminescence measurements for liquid and film using a PerkinElmer LS 45 luminescence spectrometer for optical
    characterization
  • Cyclic voltammetry for the electrochemical characterization of materials using an EG&G Model 362 scanning potentiostat and BAS low-volume electrochemical cell setup.